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Using this sample and an ordinary Geiger counter, Libby and Anderson established the existence of naturally occurring carbon-14, matching the concentration predicted by Korff. Fortunately, Libby’s group developed an alternative. They surrounded the sample chamber with a system of Geiger counters that were calibrated to detect and eliminate the background radiation that exists throughout the environment.The assembly was called an “anti-coincidence counter.” When it was combined with a thick shield that further reduced background radiation and a novel method for reducing samples to pure carbon for testing, the system proved to be suitably sensitive.Based on Korff’s estimation that just two neutrons were produced per second per square centimeter of earth’s surface, each forming a carbon-14 atom, Libby calculated a ratio of just one carbon-14 atom per every 10 carbon atoms on earth.Libby’s next task was to study the movement of carbon through the carbon cycle.In a system where carbon-14 is readily exchanged throughout the cycle, the ratio of carbon-14 to other carbon isotopes should be the same in a living organism as in the atmosphere.However, the rates of movement of carbon throughout the cycle were not then known.Top of page You read statements in books that such and such a society or archeological site is 20,000 years old.We learned rather abruptly that these numbers, these ancient ages, are not known accurately; in fact, it is at about the time of the First Dynasty in Egypt that the first historical date of any real certainty has been established.” —Willard Libby, Nobel Lecture, 12 December 1960 The concept of radiocarbon dating focused on measuring the carbon content of discreet organic objects, but in order to prove the idea Libby would have to understand the earth’s carbon system.

The concept of radiocarbon dating relied on the ready assumption that once an organism died, it would be cut off from the carbon cycle, thus creating a time-capsule with a steadily diminishing carbon-14 count.

Dedicated at the University of Chicago on October 10, 2016.

In 1946, Willard Libby proposed an innovative method for dating organic materials by measuring their content of carbon-14, a newly discovered radioactive isotope of carbon.

He reasoned that a state of equilibrium must exist wherein the rate of carbon-14 production was equal to its rate of decay, dating back millennia.

(Fortunately for him, this was later proven to be generally true.) For the second factor, it would be necessary to estimate the overall amount carbon-14 and compare this against all other isotopes of carbon.

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